Maleic anhydride 72 has been used extensively in the textiles and fibers industry. Pdf production of maleic anhydride from oxidation of nbutane. Apic 2015 top 10 maleic anhydride producers 2015 company location capacity ktpa % of total huntsman corporation united states 154 5. In this context, the electricity usage, amount of nbutane and oxygen required for the production of maleic anhydride were modified based on the information declared in the technical report abbas. Maleic anhydride chemical economics handbook ceh ihs. The first commercial process for ma production was put into use by national aniline and chemical in 1928. Applications so vast, its broad detailed discussion is well beyond the ability of one book chapter to capture. Recovery of byproduct maleic anhydride in phthalic. In recent years, demand for maleic anhydride has been growing at modest rates in north america and europe, but more vigorously in the middle east and southeast asia.
Sep 02, 20 as a large consumer of maleic anhydride for the production of malic and fumaric acids, bartek ingredients has a long term commitment to the production of this industrial commodity. D1493 test method for solidification point of industrial organic chemicals. Maleic anhydride process design enthalpy physical chemistry. Reactors and separations design project phthalic anhydride production we are continuing our evaluation of process alternatives for the production of phthalic anhydride via the catalytic oxidation of o xylene. How was the yield in maleic anhydride improved, over the years. Reports emphasize developments for 1,4butanediol from maleic anhydride via dimethyl maleate that have potential implications for the chemical and energy industries customer logins obtain the data you need to make the most informed decisions by accessing our extensive portfolio of information, analytics, and expertise.
Maleic anhydride, maleic acid, and fumaric acid by timothy r. Production of maleic anhydride from oxidation of nbutane by sajjad. Energy recovery is a key factor in the economic production of maleic anhydride. Maleic anhydride series products are essential to the production of a multitude of resins and plastics, agricultural and industrial chemicals, petroleum additives, paper sizing, water treatment chemicals, epoxy curing agents, artificial sweeteners. Maleic anhydride was traditionally produced by the oxidation of benzene or other aromatic compounds. Production of maleic anhydride biomedical engineering. Fluid mechanics, heat transfer, thermodynamics design. It is through this reaction that maleic anhydride converted to many pesticides and pharmaceuticals. Content of my lecture example of catalytic heterogeneous vapor phase oxidation of alkanes. Development and validation of the mathematical model for synthesis. Maleic anhydride is also widely used as a chemical intermediate in multiple industrial processes.
Maleic anhydride manufacture from nbutane fixedbed technology maleic anhydride man is a multifunctional chemical intermediate with applications in several fields of the chemical process industries cpi. It used the weiss and downs process employing benzene as a raw material. Its major end use is as feedstock in the production of unsaturated polyester resins upr. Mangili and others published environmental analysis of the maleic anhydride production. Recovery of byproduct maleic anhydride in phthalic anhydride. Furan and maleic anhydride were converted to phthalic anhydride in two reaction steps. Maleic anhydride market global market research reports. Xylene is flammable, so keep it away from flames and hot plates.
A process flow diagram for the reactor section of the maleic anhydride process is shown in. Maleic anhydride is a chemical compound with multiple applications in the chemical industry. Future applications are anticipated to be numerous given the versatility and usefulness of the product. Referenced documents purchase separately the documents listed below are referenced within the subject standard but are not provided as part of the standard astm standards. Occupational exposure limits, if available, are listed in section 8. Petrotex also used their butenebased process in the early 1960s. Reactor offgases, post maleic anhydride recovery, noncondensibles from vacuum systems, tank vent gases, and waste hydrocarbon rich liquids, are all incinerated to recover energy as superheated steam. One way to offset the cost incurred in the interest of pollution control is to use the scrubber system for pollution control and to recover maleic anhydride from the scrubber solution for use or sale. Maleic anhydride is produced by the following reaction. Maleic anhydride test description specification unit test limits of measure method min. Maleic anhydride current prices petrochemicals prices. Industrial production of maleic anhydride is achieved by integration of.
Pdf the plant is designed to produce maleic anhydride by the reaction of butane with oxygen using the vanadium phosphorus oxide as a heterogeneous. Maleic anhydride demand by region in 2004 is s hown in figure 2, while figure 3 presents the details of the north american u. Maleic anhydride is a colorless to white solid that forms orthorhombic crystals and decomposes in water. Maleic anhydride is produced by the thermal oxidation of nbutane at an elevated. The global maleic anhydride market size was valued at usd 2. Capital and production cost estimates are presented for such a recovery operation. The global and chinese maleic anhydride ma industry, 202023 market research report is a professional and indepth study on the current state of the global maleic anhydride ma industry with a focus on the chinese market. The report presents global maleic anhydride demand by end use and by region for the period 19982015. Maleic anhydride is a classic substrate for dielsalder reactions. Maleic anhydride is used to manufacture 1,4butanediol bdo, which has a high demand from the textile industry and the manufacturers of tetrahydrofuran thf and. D3366 test method for color of maleic anhydride and phthalic anhydride in the molten state and after heating platinumcobalt scale d3438 practice for sampling and handling naphthalene, maleic anhydride, and phthalic anhydride. Pdf oxidation of benzene to maleic anhydride in a fluidized. As a large consumer of maleic anhydride for the production of malic and fumaric acids, bartek ingredients has a long term commitment to the production of this industrial commodity. Pastillators are equipped with several trays internally, which are cooled with cold water generated in a refrigerator unit.
Astm d3504 96 standard specification for maleic anhydride. Phthalic anhydride is a white lustrous needles solid that is slightly soluble in water. This steam can be used to supply energy to integrated units. An occupationally exposed woman 65 kg at a concentration of maleic anhydride equivalent to the mak value 0. In the present study, synthesis of ethylene maleic anhydride copolymer was performed which contained pentachlorophenol or 8hydroxy quinoline.
Fluid mechanics, heat transfer, thermodynamics design project production of maleic anhydride we continue to investigate the feasibility of constructing a new, grassroots, 40,000 tonney, maleic anhydride facility. Polyethylene codipentachlorophenyl diacrylate, emapenta. Che 455 fall 2009 major 1 phthalic anhydride production. Renewable production of phthalic anhydride from biomass. Global maleic anhydride market industry analysis report. The report provides key statistics on the market status of the maleic anhydride ma manufacturers and is a valuable. Application of maleic anhydride in coatings, adhesives and. Product description and handling guide maleic acid dibutyl ester dbm page 1 of 4 maleic acid dibutyl ester dibutyl maleate cas no. Longterm health effects prolonged vapor contact to maleic anhydride may cause conjunctivitis and photophobia sensitivity of the eye to light. The report provides key statistics on the market status of the maleic anhydride ma manufacturers and is a valuable source of guidance and direction for. Unlock content over 79,000 lessons in all major subjects. Maleic anhydride mak value documentation, 1992 the mak. Maleic anhydride market 2017 global industry trends, share.
Mummey, and yeongjen kuo huntsman petrochemical corporation austin laboratories 7114 north lamar boulevard austin, texas 787522310 submitted for kirk online april 26, 2001 adobe pdf file created on july 24, 2001. Maleic anhydride 95 100% 108316 get medical attention immediately. Sodium ions and pyridine are particularly effective, even at concentrations below 0. These laminating resins, which have high structural strength and good dielectric properties, have a variety of applications in automobile bodies, building panels, molded boats, chemical storage. Man is an organic compound, in the acid anhydride class. Pune, india march 31, 2017 marketersmedia the global and chinese maleic anhydride market, 20122022 industry research report is a professional and indepth study on the current state of the global maleic anhydride industry with a focus on the chinese market. Future applications are anticipated to be numerous given the versatility and usefulness of.
Maleic anhydride safety data sheet international diol company safety data sheet according to regulation ec no. Specifications for maleic anhydride parameter value molecular formula c4h2o3 mol wt 98. Reassessment of the one exemption from the requirement of. In the case of maleic anhydride, epa made specific adjustments to the dietary exposure assessment to account for the use limitation of maleic anhydride as an inert ingredient in pesticide formulations applied to apples with a minimum preharvest interval of 21 days and at maximum concentration of 3. Selective oxidation for the production of chemicals. D3366 test method for color of maleic anhydride and phthalic anhydride in the molten state and after heating platinum. Maleic anhydride is used to manufacture 1,4butanediol bdo, which has a high demand from the textile industry and the manufacturers of tetrahydrofuran thf and polyurethane pu. Ingestion of maleic anydride is toxic and may cause digestive tract burns. The mass production capabilities coupled with a broad synthetic platform have powered maleic anhydride to an incredibly diverse range of commercial applications. Maleic anhydride west europe molten contract price ddp 0.
Maleic anhydride is a highly reactive chemical intermediate with present and potential uses in practically every field of industrial chemistry. Appearance molten briquettes colour 20 apha astm336674 purity 99. Maleic anhydride chain world market overview anna zhao na chemicals committee meeting at apic 2015 seoul, 8 may 2015. Other applications where maleic anhydride is used include the production of agricultural chemicals, maleic acid, copolymers, fumaric acid, lubricant additives, surfactants and plasticizers. Production of maleic anhydride background maleic anhydride is a versatile chemical intermediate used to make unsaturated polyester resins, lube oil additives, alkyd resins, and a variety of other products. Maleic anhydride manufacture technology free library.
As part of the feasibility study, we would like you to investigate some. Other significant markets for maleic anhydride include lubricating oil additives, production of organic acids fumaric, malic, and succinic, and copolymers. From single crystal xray diffraction data 10, maleic anhydride is a nearly planar molecule with the ring oxygen atom lying 0. Maleic anhydride market global industry analysis, size. Pdf production of maleic anhydride from oxidation of n. The report provides key statistics on the market status of the maleic anhydride manufacturers and is a. It was used for work in 1928, on the reaction between maleic anhydride and 1,3butadiene, for which otto paul hermann diels and kurt alder were awarded the nobel prize in 1950. Bdo was the second largest outlet for maleic anhydride in 2012.
Electronic pdf the global maleic anhydride market size is projected to reach usd 4. Other key applications for maleic anhydride include the production of agricultural chemicals, lubricant additives, copolymers, malic acid, fumaric acid, surfactants and plasticizers. Maleic anhydride current prices petrochemicals prices database. Substance any concentration shown as a range is to protect confidentiality or is due to batch variation. Increasing demand for unsaturated polyester resins upr and 1,4butanediol bdo are expected to augment market growth over the forecast period. It is used for the production of polyester and alkyd. The reaction will be conducted under reflux conditions. This part of the plant contains 14 pastillators depending on the required capacity. A route to renewable phthalic anhydride 2benzofuran1,3dione from biomassderived furan and maleic anhydride furan2,5dione is investigated. Maleic anhydride causes severe burns and may produce an allergic skin reaction in sensitive individuals. Specifically, when maleic anhydride is converted to maleic andor fumaric acid, it is a great preservative or flavor enhancer.
Reactors and separations design project phthalic anhydride. Preliminary pfd for reactor loop of maleic anhydride production process. Product description and handling guide maleic acid dibutyl. In 1995, global production of maleic anhydride was estimated at 1. The user has requested enhancement of the downloaded. Increasing demand for unsaturated polyester resins upr and 1,4butanediol bdo are expected.
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